Many substances with different chemical and physical properties, from diamonds to graphite, are made up of carbon atoms. Amorphous forms of solid carbon do not have a fixed crystal structure and consist of structural units–nanosized graphene particles. A team of physicists from RUDN University studied the structure of amorphous carbon and suggested classifying it as a separate type of amorphous solid bodies: a molecular amorphic with enforced fragmentation. The results of the study were published in the Fullerenes, Nanotubes and Carbon Nanostructures journal.
Solid carbon has many allotropic modifications. It means that substances with different chemical and physical properties can be built from one and the same atoms arranged in different structures. The variety of carbon allotropes is due to the special properties of its atoms, namely their unique ability to form single, double, and triple valence bonds. If, due to certain reaction conditions, only single bonds are formed (i.e. the so-called sp³-hybridization takes place), solid carbon has the shape of a three-dimensional grid of tetrahedrons, i.e. a diamond. If the conditions are favorable for the formation of double bonds (sp²-hybridization), solid carbon has the form of graphite–a structure of flat layers made of comb-like hexagonal cells. Individual layers of this solid body are called graphene. These two types of solid carbon structures are observed both in ordered crystals and non-ordered amorphous bodies. Solid carbon is widely spread in nature both as crystalline rock (graphite or diamond) deposits and in the amorphous form (brown and black coal, shungite, anthraxolite, and other minerals).
Unlike its crystalline form, natural amorphous carbon belongs to the sp² type. A major study of the structure and elemental composition of sp² amorphous carbon was conducted at the initiative and with the participation of a team of physicists from RUDN University. In the course of the study, the team also took spectral measurements using photoelectronic spectroscopy, inelastic neutron scattering, infrared absorption, and Raman scattering. Based on the results of the study, the team concluded that sp² amorphous carbon is a fractal structure based on nanosized graphene domains that are surrounded by atoms of other elements (hydrogen, oxygen, nitrogen, sulfur, and so on). With this hypothesis, the team virtually re-wrote the history of amorphous carbon that has been known to humanity since the first-ever man-made fire.
“The discovery and experimental confirmation of the graphene nature of the ‘black gold’ will completely change the theory, modeling, and interpretation of experiments with this class of substances. However, some questions remain unanswered. What does solid-state physics make of this amorphous state of solid carbon? What role does amorphous carbon with sp²-hybridization play in the bigger picture? We tried to find our own answers,” said Elena Sheka, a Ph.D. in Physics and Mathematics, and a Consulting Professor at the Faculty of Physics and Mathematics and Natural Sciences, RUDN University.
The team spent two years thoroughly studying the nature of amorphous carbon. Other results of this ambitious project were published in Fullerenes, Nanotubes and Carbon Nanostructures, Journal of Physical Chemistry C, and Journal of Non-Crystalline Solids, Nanomaterials. Together, these works confirm a breakthrough achieved by the physicists of RUDN University in this complex field of physics.
“We have analyzed many studies on amorphous sp² carbon from the point of view of our general understanding of amorphous solid bodies. Based on our research, we can confirm that it belongs to a new type of amorphous substances,” added Elena Sheka from RUDN University.
References: E. F. Sheka , Ye. A. Golubev & N. A. Popova, “Amorphous state of sp² solid carbon”, Fullerenes, Nanotubes and Carbon Nanostructures, 2020. https://www.tandfonline.com/doi/full/10.1080/1536383X.2020.1815713
Provided by RUDN University