New Synthetic Route For Biofuel Production (Chemistry)

Compared to previous methods, the team has achieved a high yield and selectivity under less aggressive reaction conditions.

A German-Chinese research team has found a new synthetic route to produce biofuel from biomass. The chemists converted the substance 5-hydroxymethylfurfural (HMF) produced from biomass into 2,5-dimethylfuran (DMF), which could be suitable as a biofuel. Compared to previous methods, they achieved a higher yield and selectivity under milder reaction conditions. The team led by Dr. Baoxiang Peng and Professor Martin Muhler from the Laboratory of Industrial Chemistry at Ruhr-Universität Bochum (RUB) and the group led by Professor Christof Hättig from the RUB Chair for Theoretical Chemistry described the method together with colleagues from Changzhou, China, in the journal Angewandte Chemie. The final version of the article has been online since 22 January 2021.

The work was part of the German-Chinese research cooperation “Novel Functional Materials for Sustainable Chemistry”, which is supported by the German Research Foundation.

Better fuel than ethanol

“DMF would be well-suited as a biofuel, as it has a higher octane number than ethanol, a better energy intensity and  an ideal boiling point of 92 to 94 degree Celsius,” explains Baoxiang Peng. Although the conversion from HMF into DMF has been researched intensively, there are several hurdles. DMF production requires relatively harsh reaction conditions, such as high hydrogen pressure, and often only creates a small quantity of the desired product, while also forming unwanted by-products. Researchers are thus looking for new ways to efficiently trigger the reaction under milder conditions. This was achieved in the current work.

Formic acid as the key to success

The team carried out the reaction in the presence of formic acid and hydrogen. Palladium nanoparticles were used as a catalyst. In doing so, the chemists achieved a five-times larger reaction rate than those reported with previous methods. The addition of formic acid, in particular, played a crucial role in creating favourable reaction conditions, as shown by the researchers in their detailed investigations.

They performed the reaction with various additives and compared the yield and selectivity, which were best in the presence of formic acid. The substance facilitates a faster reaction pathway and also prevents the occurrence of unwanted side reactions.

Funding: The German Research Foundation supported the work (funding code MU 1327/10-1 and Ha 2588/9-1).

Featured image: The Bochum-based catalysis team: Baoxiang Peng (left) and Martin Muhler © RUB, Rohlf


Reference: Bin Hu et al.: Formic acid-assisted selective hydrogenolysis of 5-Hydroxymethylfurfural to 2,5-Dimethylfuran over bifunctional Pd nanoparticles supported on N-doped mesoporous carbon, Angewandte Chemie International Edition, 2021, DOI: 10.1002/anie.202012816 https://onlinelibrary.wiley.com/doi/10.1002/anie.202012816


Provided by Ruhr Universität Bochum

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